Listening materials:
http://www.listenaminute.com – these listening exercises are usually a bit easier, so good for ESL learners at elementary and pre-intermediate level.
http://learnenglish.britishcouncil.org/en/
Materials for younger students:
Unfortunately, Harrow Academy UK does not accept students under the age of 17. However, any younger students might like to take a look here:
http://learnenglishkids.britishcouncil.org/en/fun-with-english
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